Dr. Jarnuzi Gunlazuardi
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To Group Members:
2019 Weekly Meeting is scheduled every Monday 14:00 - 16:00
Room: G Building, third floor, postgraduate meeting room
My Brief CV (jarnuzi@ui.ac.id):
Jarnuzi Gunlazuardi earned PhD (1993) and Master (1990) in Environmental Analytical Chemistry from Ehime University, Japan, under Prof. Tadaaki Wakimoto and Prof. Ryo Tatsukawa. His dissertation’s work is on the development of precise analytical method for specific congeners analysis of persistent organochlorine pollutant (e.g. Polychlorinated Mono Terpenes), based on chromatographic sciences (column chromatographic and GCMS). He took postdoctoral work, a short visiting scientist, at The Department of Chemistry and at The School of Chemical Engineering and Advanced Materials, University of New Castel, upon Tyne, UK , [Dr. P.A. Christensen (Photo electro catalytic Detoxification of Water; Development of Novel Photo catalyst and Photo catalytic Reactor), (Nov. ’95 ~Feb.’96; July ~ Sept. 1997; June-August 1999; Oct-Dec 2003). His current research projects are (1) Solar Hydrogen Energy (Modified Dyes Sensitized Solar Cell Having Catalysis Zone Extension For a Water Splitting), a Bilateral Exchange Program JSPS-DGHE Joint Research Projects; (2) The Chemistry of Functional Material for Health, Energy, and The Environment, a DGHE Project.
Key Skills and Capabilities
Photocatalysis and Photoelectrocatalysis –employing titanium dioxide- for a water and indoor air treatment; Electroanalysis: development of chemically modified electrodes for general and specific sensing; Analysis of Persistent Organochlorine Compounds in Environmental Samples (by GC-MS).
Specific Expertise
Spectrometry; Electrochemistry; Gas Chromatography–Mass Spectrometry.
Research & Research Group Activities
My research is mainly dealing with specific surface phenomena that can be applied to various chemical processes and analysis, and mostly dedicated to challenge a health and environmental problems. In doing so, I have focused the study either on photocatalysis and electrochemistry processes on specific surface ( e.g. titanium dioxide, modified carbon electrode etc.).
My work on, so called, "TiO2 photocatalysis" bring me involve in developing photocatalytic reactors for a water treatment and an indoor air purifier systems. Our inner wall glass column tube coated titanium dioxide (IWGCT-TiO2) has a potential application for small scale photocatalytic reactor, which may be applied for a house hold water treatment or air purifier and oxidation unit in a Total Organic Carbon Analyzer apparatus.
I am also interested combining photocatalytic system with an electrochemical system. My work on this matter was initiated during my several short stay in Professor P.A. Christensen Laboratory (Dept. of Advance Material Science, Faculty of Science Agriculture and Engineering, University of Newcastle, upon Tyne, UK).
By applying Prof Christensen’s photoelectrochemical system lead me developes a what we called Chemical Oxygen Demand (COD) sensor. This was invented as a result of careful observation and evaluation of the very first (or instant) photocurrent evolution and decay, which nicely give a charge that quantitatively proportional to the mole value of oxidize-able chemical, in adjacent to TiO2 surface, regardless of their chemical species. It is well understood that upon proper light exposure, the TiO2 surface will generate electron (e-) and positive hole (h+) pair, and it is the hole (valence band) that oxidize directly or indirectly oxidize able chemical species in or near by TiO2 surface (via generation of hydroxyl radical, ∙OH). While the exited electron (in conduction band) is drawn away and subsequently transferred to a dissolved oxygen (via counter electrode) in the water that immerse both immobilized TiO2 and respected counter electrode. This flow of electrons (monitored as photocurrent) at the early minute upon light illumination create sharp peak of current vs time before reach a steady state, and integration of the peak give a charge that proportional to chemical oxygen demand (COD) of the bulk water that immerse the TiO2. However. it was not our side who first published very nice description and evaluation of this phenomenon. In fact, during our struggle time to understand the phenomenon and possible utilization, Zhao et all published an excellent paper on this matter [Zhao, H., Jiang, D., Zhang, S., Catterall Kylie, and John, R: “Development of Direct Photoelectrochemical Method for Determination of Chemical Oxygen Demand”. Anal. Chem. (2004) 76: 155-160].
While developing a method to immobilize of TiO2 on various substrate we found a clear TiO2 suspension, due its nanosize (approximately 5 to 9 nm), that facilitate us to coat a substrate with TiO2 (either in anatase or rutile) at room temperature. This stuff is having potentiality to coat a wall of indoor room (living room, office, and vehicles) that will show a self cleaning effect.
Extensive test and development for both COD sensor and room temperature coating of the indoor wall are in progress.
Current research projects are (1) Solar Hydrogen
Energy (Modified Dyes Sensitized Solar Cell Having Catalysis Zone Extension For
a Water Splitting), a Bilateral Exchange Program JSPS-DGHE Joint Research
Projects; (2) The Chemistry of Functional Material for Health, Energy, and The
Environment, a DGHE Project.
Selected Publications:
- Slamet, Ratnawati, Jarnuzi Gunlazuardi, Eniya
ListianiDewi: “Enhanced photocatalytic activity of Pt deposited
on titania nanotube arrays for the hydrogen production with glycerol as a
sacrificial agent” International Journal of Hydrogen Energy, Volume 42, Issue 38, 21 September
2017, Pages 24014-24025 - Fisli,
A., Ridwan, Krisnandi,
Y.K., Gunlazuardi,
J. (2017): “Preparation and characterization of Fe3O4/SiO2/TiO2 composite for methylene blue removal in water” International Journal of Technology 8 (1),
pp. 76-84 - Syafaat, F.,Gunlazuardi,
J.: “Zinc-porphyrin-imide type sensitized TiO2 nanotube arrays as
photoactive electrode in a dyes sensitized solar cell “ IOP
Conf. Series: Materials Science and Engineering 1234567890 188 (2017)
012023 doi:10.1088/1757-899X/188/1/012023 - Ichzan, A.M.,Gunlazuardi, J.,Ivandini,
T.A.: “Preparation of boron doped diamond modified by iridium for
electroreduction of carbon dioxide (CO2) “ IOP Conf.
Series: Materials Science and Engineering 1234567890 188 (2017) 012030
doi:10.1088/1757-899X/188/1/012030
5. Jasril,Gunlazuardi, J.,Ivandini,
T.A.:” Preparation of platinum-modified boron-doped diamond for
electroreduction of CO2 “ IOP Conf. Series: Materials Science
and Engineering 1234567890 188 (2017) 012037 doi:10.1088/1757-899X/188/1/012037
6. Firmansyah, B.D.,Ivandini, T.A.,Gunlazuardi,
J.: “Capillary electrophoresis of adenosine phosphates using boron-doped
diamond electrodes “ IOP Conf. Series: Materials Science and
Engineering 1234567890 188 (2017) 012052 doi:10.1088/1757-899X/188/1/012052
7. Yetri, N.Y.,Ivandini, T.A.,Gunlazuardi,
J.: “Preparation of copper oxide modified boron-doped diamond electrodes and
its preliminary study for CO2 reduction “ IOP Conf.
Series: Materials Science and Engineering 1234567890 188 (2017) 012011
doi:10.1088/1757-899X/188/1/012011
8. Musyarofah, N.R.R.,Gunlazuardi, J.,Einaga,
Y.,Ivandini, T.A: “Anodic stripping voltammetry of nickel ions and nickel
hydroxide nanoparticles at boron-doped diamond electrodes “ IOP Conf.
Series: Materials Science and Engineering 1234567890 188 (2017) 012020
doi:10.1088/1757-899X/188/1/012020
9. Nurlela,Wibowo, R.,Gunlazuardi, J.:
“Natural dye sensitizer from cassava (Manihot utilissima) leaves extract and
its adsorption onto TiO2 photo-anode”, IOP Conf. Series: Materials
Science and Engineering 1234567890 188 (2017) 012047
doi:10.1088/1757-899X/188/1/012047
10. Prayikaputri, P.U.,Gunlazuardi, J.,Ivandini,
T.A.: “Fabrication and characterization of micro-band boron-doped diamond
electrode for an application in adenosine phosphates sensor” IOP Conf.
Series: Materials Science and Engineering 1234567890 188 (2017) 012035
doi:10.1088/1757-899X/188/1/012035
11. Aritonang, A.B., Surahman, H.,
Krisnandi, Y.K., Gunlazuardi, J. Photo-electro-catalytic performance of highly
ordered nitrogen doped TiO2 nanotubes array photoanode (2017)
IOP Conference Series: Materials Science and Engineering, 172 (1), art. no.
012005,
12. Styarini, D., Gunlazuardi, J.
Feasibility study on the development of reference material of pesticide in
black tea (2017) Periodico Tche Quimica, 14 (27), pp. 146-154.
- Supriyono, Krisnandi,Y.K., Gunlazuardi,J.(2016):“Band gap
energy modification of TiO2 photoelectrode by PbS/CdS
quantum dot to enhance visible region photocurrent”, International Journal of ChemTech Research,
Volume 9, Issue 7, Pages 191-198 - Supriyono,
Yuni Krisyuningsih Krisnandi, and Jarnuzi Gunlazuardi (2016) : “Electrodeposition
of gold nanoparticles on mesoporous TiO2 photoelectrode to
enhance visible region photocurrent” AIP Conference Proceedings 1729,
020049; doi: 10.1063/1.4946952 - Supriyonoa,
Hedi Surahmana, Yuni Krisyuningsih Krisnandia, and Jarnuzi Gunlazuardia:
“Preparation and characterization of transparent conductive SnO2-F thin
film deposited by spray pyrolysis: relationship between loading level and
some physical properties” Procedia Environmental Sciences 28
( 2015 ) 242 – 251, doi: 10.1016/j.proenv.2015.07.031 - Ratnawati, Jarnuzi
Gunlazuardi and Slamet: ” Synthesis of TiO2 Nanotube
Arrays by Sonication Aided Anodization and Its Application for Hydrogen
Generation from Aqueous Glycerol Solution” MATEC Web of Conferences 28,
01001 (2015), http://dx.doi.org/10.1051/matecconf/20152801001 - Ratnawati,
Jarnuzi Gunlazuardi, Slamet: “Development of titania nanotube arrays: The roles
of water contentand annealing atmosphere” Materials Chemistry and
Physics 160 (2015) 111-118 http://dx.doi.org/10.1016/j.matchemphys.2015.04.013 - Wulan
Tri WAHYUNI, Tribidasari A. IVANDINI, Prastika K. JIWANTI, Endang
SAEPUDIN, Jarnuzi GUNLAZUARDI, and Yasuaki EINAGA: “Electrochemical
Behavior of Zanamivir at Gold-Modified Boron-Doped Diamond Electrodes for
an Application in Neuraminidase Sensing” Electrochemistry, 83(5),
357–362 (2015), http://dx.doi.org/10.5796/electrochemistry.83.357 - Ratnawati
Ratnawati; Jarnuzi Gunlazuardi, Eniya Listiani Dewi,
and Slamet :“Effect of NaBF4 addition on the anodic synthesis of TiO2 nanotube
arrays photocatalyst for production of hydrogen from glycerol-water
solution”, International Journal of Hydrogen
Energy, , 39, 16927-16935, 2014. - Oman
Zuas, Jin Seog Kim, and Jarnuzi Gunlazuardi: “Influence
of Operational Parameters on the Photocatalytic Activity of Powdered TiO2
for the Reduction of CO2” Indonesian Journal of Chemistry (Indo.
J. Chem.) vol. 14 no. 2 pp. 122-130, July 2014 - Adel
Fisli, Saeful Yusuf, Ridwan, Jarnuzi Gunlazuardi*): “Preparation
and Characterization of Magnetite-Silica Nanocomposite as Adsorbents
for Removal of Dyes from Environmental Water Samples“, Journal
of Advance Material and
Engineering Technology, Vol. 896 (2014) pp 525-531 - Oman Zuas, Yuni
Krisyuningsih Krisnandi, Widayanti Wibowo,
Jin Seog Kim, Jarnuzi Gunlazuardi*):
“Copper-Zinc-Titania
Nanocomposite as Catalyst
for CO2 Photo-Reduction: A Surface Deactivation
Study” Journal of Advance
Material and Engineering Technology, 896 (2014) pp 134-140 - Adel
Fisli, Rahmi Saridewi, Sari Hasnah Dewi, Jarnuzi Gunlazuardi:
“Preparation and Characterization of Fe3O4/TiO2 Composites by
Heteroagglomeration” Advanced Materials Research Vol.
626 (2013) pp 131-137. - T.A.
Ivandini, L. Wijaya, J.Gunlazuardi and Y. Einaga: ”
Modification of Gold Nanoparticles at Carbon Electrodes and Applications
for Arsenic (III) Detections”, J Makara Seri Sains Vol. 16, No. 1, (2012) - Ratno Nuryadi, Zico Alaia Akbar, Jr., Agus Hadi S. Wargadipura, and Jarnuzi Gunlazuardi: “Formation of
TiO2Thin Film for Dye-Sensitized Solar Cell Application Using
Electrophoresis Deposition” AIP
Conf. Proc.; Vol.1284, (2010) pp.148-153;
doi:10.1063/1.3515539” - Oman Zuas, Widayanti Wiobowo, Jarnuzi Gunlazuardi, Hery Haerudin, Kim, Jin Seog: “Photo-conversion
of CO₂ into CO over TiO₂ Nano-catalysts, Synthesized by
Co-precipitation method” 44th of
Analytical Science Proc., 5, 119-11, (2010) - Oman Zuas, Widayanti Wiobowo, Jarnuzi Gunlazuardi, Hery Haerudin, Kim, Jin Seog: “Characterization
and photocatalytic reduction of CO₂ over Zn-doped TiO₂ Nanopower Synthesized by Co-precipitation
Method” 45th of Analytical Science Proc.,.11, 274-274, (2010) - Slamet,
Hosna W. Nasution, Ezza Purnama, Kapti Riyani and Jarnuzi
Gunlazuardi: “Effect of Copper Species in a Photocatalytic
Synthesis of Methanol from Carbon Dioxide over Copper-doped Titania
Catalysts”,World Applied Sciences Journal 6 (1): 112-122, 2009 - M.Nurdin,
W. Wibowo, Supriyono, M.B. Febrian, dan J. Gunlazuardi*):
”Pengembangan Metoda Baru untuk Penentuan COD (Chemical Oxygen Demand)
Berbasis Fotoelektrokatalisis: Karakterisasi Elektroda Kerja Lapis Tipis
TiO2¬/ITO”; J. Makara Seri Sains Vol 13, No. 1 [April 2009]. - Slamet,
Hosna W. Nasution, Ezza Purnama, Soleh Kosela , Jarnuzi
Gunlazuardi*: “Photocatalytic reduction of CO2 on copper-doped Titania
catalysts prepared by improved-impregnation method” Catalysis
Communications 6 (2005) 313–319 - J.Gunlazuardi and
Winarti A Lindu: “Photocatalytic degradation of pentachlorphenol in
aqueous solution employing immobilised TiO2 supported on titanium metal
“Journal of Photochemistry and PhotoBiology A: Chemistry, 173(1): 51–55.
[2005] - Slamet,
J. Gunlazuardi and Soleh Kosela: “Photoreduction of CO2 on TiO2
Photocatalysts Powders” Journal ACGC, Vol 17, 2004 - Rachmat
Triandi Tjahjanto dan J.Gunlazuardi: “Preparasi Lapisan Tipis
TiO2 sebagai Fotokatalis: Keterkaitan antara Ketebalan dan Aktivitas
Fotokatalisis”, Makara, Jurnal Penelitian Universitas Indonesia, vol. 5,
no. 2, Seri Sains, hal. 81-91, Desember 2001 - J.C.
Harper, P.A. Christensen, T.A. Egerton, T.P. Curtis and J.
Gunlazuardi: “Effect of catalyst type on the kinetics of the
photoelectrochemical disinfection of water inoculated with E.coli” Journal
of Applied Electrochemistry 31:623-628, 2001 - E.Suhardono, J.Gunlazuardi,
M.Mulyono, dan Retno Ambarwati : ”Studi Laboratorium Degradasi Fenol
Secara Fotokatilitik Dengan uspensi TiO2 Pada Reaktor Kolam dan Kolom”, Lembaran
Publikasi LEMIGAS, no.1, vol.34 :12-21, 1999
I.M.
Butterfield , P.A. Christensen, T.P. Curtis and J. Gunlazuardi:
“Water Disinfection Using An Immobilised Titanium Dioxide Film In A
Photochemical Reactor With Electric Field Enhancement”, J.Water Research,
vol.31, No.3, p.675, 1997
y submitted Patent:
-
· J Gunlazuardi, M Nurdin, H. Surahman, Supriyono: ”Peralatan
pengukur kebutuhan oksigen kimiawi sebagai indikator tingkat pencemaran air dan
proses pembuatannya” No Pendaftaran P00200900501, No pengumuman 051.1093
Granted Patent:
- E. Suhardono; J.Gunlazuardi, M. Nasikin: "Metode penghilangan polutan organic didalam air limbah buangan dengan matahar sebagai sumber radiasinya". [Paten oleh PPPTMGB LEMIGAS; disetujui pemberian paten oleh Dirjen HAKI Dep. Kehakiman dan HAM RI tanggal 3 Nopember 2004, Nomor Paten ID 0 014 5
- E. Suhardono; J.Gunlazuardi, M. Nasikin: "Reaktor kolom berbahan dasar gelas kuarsa untuk mendestruksi senyawa organik dan mematikan mikroorganisme dalam air". [Paten oleh PPPTMGB LEMIGAS; disetujui paten oleh Dirjen HAKI Dep. Kehakiman dan HAM RI, 24 Desember 2004 Nomor Paten: ID 0 014 914
Current Research grants
- JSPS-DGHE Bilateral Exchange: JSPS-DGHE Joint Research (2015-2017); Research Field: Material Chemistry:
photo-catalyst for hydrogen production, title "Modified QD Sensitized Solar Cell Having Catalyst Zone Extension As a New Approach To Produce Hydrogen From Water By Visible Light". Collaborative work with Prof Hisao Yoshida, Department
of Interdisciplinary Environment Graduate School of Human and Environmental
Studies Kyoto University -
Titania Photo Electro Catalysis (TiPEC) Research Cluster Scheme (2015-2017); Title: "Highly Ordered Titania Nanotube for an Artificial
Photosynthesis: (1) A New Environmental Friendly Energy Generation System and (2) Novel Corrosion
Prevention System. [Funded by University of Indonesia]" - Education and Employment
- BSc. (1979) and Drs. (1984) , Department of Chemistry, University of Indonesia
- MSc (1990 and PhD (1993), Environmental Analytical Chemistry, Department of Environmental Conservation, Ehime University.
- Visiting Researcher University of Newcastle upon Tyne, UK , [Dr. P.A. Christensen (Photoelectrocatalytic Detoxification of Water; Development of Novel Photocatalyst and Photocatalytic Reactor)], (November 1995 ~ Februari 1996; Juli ~ Septemer 1997; Juni-Agustus 1999; Oktober-Deember 2003).
- Junior Lecturer (1986), Department of Chemistry, University of Indonesia
- 1987 – 1993 (leave for a postgraduate study)
- Lecturer (1997), Department of Chemistry, University of Indonesia
- Senior Lecturer (2003 ~ ), Department of Chemistry, University of Indonesia
Managerial Experience:
- Head of The Postgraduate in Chemistry, Faculty of Science, University of Indonesia (2008)
- Head of The Department of Chemistry, Faculty of Science, University of Indonesia (2004-2007)
- Secretary of The Postgraduate in Chemistry, Faculty of Science, University of Indonesia (2000-2003)
Others:
- Editor Team of Journal Makara Seri Sains
More further information of me [in Indonesian Language Bahasa Indonesia]
Another web based activity of me on TiO2 Photocatalysis [in Indonesian Language, Bahasa Indonesia]
To Group Members: Current Weekly Meeting is scheduled at every Thursday 14:00 - 16:00
Available Instrumentations
Links
Dept. of Cemistry UI Page
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